Dumping Domain Controller Hashes via wmic and Vssadmin Shadow Copy
This quick labs hows how to dump all user hashes from the DC by creating a shadow copy of the C drive using vssadmin - remotely.
This lab assumes the attacker has already gained administratrative access to the domain controller.
Execution
Create a shadow copy of the C drive of the Domain Controller:
wmic /node:dc01 /user:administrator@offense /password:123456 process call create "cmd /c vssadmin create shadow /for=C: 2>&1"
Copy the NTDS.dit, SYSTEM and SECURITY hives to C:\temp on the DC01:
Below shows the above command executed on the attacking machine (right) and the files being dumped to c:\temp on the DC01 on the left:

Mount the DC01\c$\temp locally in order to retrieve the dumped files:

Now, of you go extracting hashes with secretsdump as shown here:
Dumping Domain Controller Hashes Locally and RemotelyObservations
A quick note for defenders on the proces ancestry:

and of course commandlines:

as well as service states:

...and of course the lateral movement piece:

References
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